Tetrahedron

Octaline and decalone derivatives from a new annulation reaction in enamine field

G Pitacco, A Risaliti, ML Trevisan, E Valentin

文献索引：Pitacco,G. et al. Tetrahedron, 1977 , vol. 33, p. 3145 - 3148

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被引用次数: 14

摘要

An octaline system is obtained from the reaction between 2-cyclohexenyl-1-morpholino- ethene and β-nitrostyrene, carried out under kinetic control. By hydrolysis, it is converted to a 1-decalone derivative, which is also a kinetic control product. The stereochemical aspects of formation and equilibration of the products are examined.