Tetrahedron

Acyloxylactonisations mediated by lead tetracarboxylates

IF Cottrell, AR Cowley, LJ Croft, L Hymns, MG Moloney…

文献索引：Cottrell, Ian F.; Cowley, Andrew R.; Croft, Laura J.; Hymns, Lauren; Moloney, Mark G.; Nettleton, Ewan J.; Kirsty Smithies; Thompson, Amber L. Tetrahedron, 2009 , vol. 65, # 12 p. 2537 - 2550

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被引用次数: 10

摘要

The reaction of lead (IV) tetracarboxylates with carboxylic acids containing unsaturated side chains has been found to give acyloxy lactone products in a diastereoselective process; the reaction can be extended to lead (IV) tetrazolates to give the analogous outcome. Mechanistic implications of these results are discussed.