The Synthesis and Reactions of 2-Chloro-5-hydroxytropone

T Nozoe, T Asao, E Takahashi…

文献索引：Nozoe,T. et al. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, # 6 p. 1310 - 1316

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被引用次数: 10

摘要

The acid hydrolysis of some polyhalotropones and some reactions of the products were investigated. The treatment of 2, 5-dichlorotropone with hydrochloric or sulfuric acid afforded 2-chloro-5-hydroxytropone (I) and a small amount of 5-chlorotropolone. The compound I gives only one kind of the methyl ether and one kind of the acetyl or benzoyl derivative. From the methyl ether, 5-amino-and 5-methylamino-2-chlorotropone were derived. The ...