The Journal of Organic Chemistry

Palladium-catalyzed coupling of aryl halides with (trimethylstannyl) diphenylphosphine and (trimethylsilyl) diphenylphosphine

SE Tunney, JK Stille

文献索引：Tunney, S. E.; Stille, J. K. Journal of Organic Chemistry, 1987 , vol. 52, # 5 p. 748 - 753

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被引用次数: 204

摘要

The palladium-catalyzed reaction of aryl halides with either (trimethylsily1) diphenylphosphine or (tri-methylstanny1) diphenylphosphine gives aryldiphenylphosphines in good yields, under relatively mild conditions (50-70" C, benzene). The reaction tolerates a number of functional groups including methyl ethers, esters, ketones, nitriles, anilides, and certain halogens. The nitro and aldehyde groups as well as compounds containing ...