Codimerization of. alpha.-olefins and conjugated dienes by a nickel-based coordination catalyst

RG Miller, TJ Kealy, AL Barney

文献索引：Miller,R.G. et al. Journal of the American Chemical Society, 1967 , vol. 89, p. 3756 - 3761

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被引用次数: 47

摘要

Abstract: The addition of a-olefins to conjugated dienes is accomplished by a catalyst derived from the interaction of bis (tri-n-butylphosphine) nickel (II) chloride with diisobutylaluminum chloride. The primary products are linear 1, 4-dienes. The catalyst affords trans-and cis-l, 4-hexadiene and 3-methyl-l, 4-pentadiene from ethylene and butadiene. The specificity in the formation of 1, Cdiene position isomers in the reactions of ...