Direct Palladium-Catalyzed Phosphinylation of Aryl Triflates with Secondary Phosphines. Its Scope and Limitations: The Synthesis of Optically Active Carboxylated 2-( …

G Martorell, X Garcías, M Janura…

文献索引：Martorell, Gabriel; Garcias, Xavier; Janura, Marcus; Saa, Jose M. Journal of Organic Chemistry, 1998 , vol. 63, # 10 p. 3463 - 3467

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被引用次数: 44

摘要

A major objective of modern organic synthesis is improving the efficiency of chemical reactions (“atom economy” as put for by BM Trost1) and phase-separation as well. 2 The advantages of using water-soluble3 and/or “fluorous-phase”-soluble reagents or catalysts to this end have been highlighted in the recent literature. We have recently embarked on a program to explore catalytic, enantioselective organometallic chemistry in ...