Preparation of the First Bench??Stable Phenyl Selenolate: an Interesting “On Water” Nucleophilic Reagent

…, S Santoro, B Battistelli, L Testaferri…

文献索引：Santi, Claudio; Santoro, Stefano; Battistelli, Benedetta; Testaferri, Lorenzo; Tiecco, Marcello European Journal of Organic Chemistry, 2008 , # 32 p. 5387 - 5390

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被引用次数: 47

摘要

Abstract In this communication we report the synthesis and the characterization of the first solid and air-stable selenolates, starting from commercially available phenylselenenyl halides and elemental zinc. These reagents were efficiently employed in the ring opening of epoxides as well as in other nucleophilic substitution and addition reactions showing an unexpected rate acceleration in water suspension at room temperature.(© Wiley-VCH ...