Oxidation of Alkylcatecholboranes with Functionalized Nitroxides for Chemical Modification of Cyclohexene, Perallylated Polyglycerol and of Poly (butadiene)
CB Wagner, A Studer
文献索引：Wagner, Christine B.; Studer, Armido European Journal of Organic Chemistry, 2010 , # 30 p. 5782 - 5786
Abstract The present communication reports on the synthesis of alkoxyamines by hydroboration of olefins with catecholborane and subsequent oxidation by using nitroxides. Oxidation occurs via a radical process and the intermediately formed C-radicals are trapped by the nitroxides to form the corresponding alkoxyamines. If functionalized nitroxides are used, the method allows incorporation of interesting functional moieties via this approach. ...
