Access to unstabilized secondary vinylphosphines by chemoselective reduction of vinylphosphinates or by P-alkylation of the primary vinylphosphine

AC Gaumont, X Morise, JM Denis

文献索引：Gaumont, A. C.; Morise, X.; Denis, J. M. Journal of Organic Chemistry, 1992 , vol. 57, # 15 p. 4292 - 4295

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被引用次数: 21

摘要

" Method A reduction of vinylphosphinates 1. Method B: P-alkylation of 3. bDetermined by'H NMR with dimethyl methylphosphonate as internal reference.'Purification by trap to trap distillation (purity higher than 95%). dDistillation under vacuum; separation from THF was unsuccessful. e Yield of crude product.