Stereoselective acyl transfer reactions controlled by the diphenylphosphinoyl group: X-ray structures of stable crystalline silylated tetrahedral intermediates
N Feeder, G Hutton, S Warren
文献索引：Feeder, Neil; Hutton, Gordon; Warren, Stuart Tetrahedron Letters, 1994 , vol. 35, # 32 p. 5911 - 5914
Abstract Acyl transfer with LDA on benzoates of single diastereoisomers of 3- hydroxyalkyldiphenylphosphine oxides in the presence of trimethylsilyl chloride gives silylated tetrahedral intermediates in carbonyl displacement reactions with the stereochemically controlled creation of two new chiral centres. X-rays reveal the stereochemistry.
