Journal of the American Chemical Society

Methyl transfers. 8. The Marcus equation and transfers between arenesulfonates

ES Lewis, DD Hu

文献索引：Lewis, Edward S.; Hu, Daniel D. Journal of the American Chemical Society, 1984 , vol. 106, # 11 p. 3292 - 3296

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被引用次数: 61

摘要

2 16X of the barriers for the two identity reactions. The application to reactions without identity reactions is much more q~ estionable, 4~-'but these difficulties are not relevant to the present work. Equation 2 is not directly applicable to experiment since the values of WR, A, and AGO are not directly measurable. Equation 2 can be converted to an experimentally useful form, if the following assumptions are made. 1. The work term,@, is structure ...