Reductive Cyclization of o-Nitrophenylazo Dyes Using Bakers' Yeast in NaOH Solution. A New Synthesis of 2-Aryl-2H-benzotriazoles and Their 1-Oxides

W Baik, TH Park, BH Kim, YM Jun

文献索引：Baik, Woonphil; Park, Tae Hong; Kim, Byeong Hyo; Jun, Young Moo Journal of Organic Chemistry, 1995 , vol. 60, p. 5683 - 5685

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被引用次数: 25

摘要

In recent years, bakers' yeast (Saccharomyces cerevisiae) has been widely employed for the stereoselective reduction of &keto esters, la a-keto esters, lb &keto phenyl sulfides, lc or a, P- unsaturated carbonyl compounds. ld Among many applications of bakers' yeast in organic synthesis, the reduction of carbonyl groups to their hydroxy groups is one of the most extensively studied. However, the mechanistic details of bakers' yeast reduction of ...