Varying the electronic structure of surface-bound ruthenium (II) polypyridyl complexes
DL Ashford, MK Brennaman, RJ Brown…
文献索引：Ashford, Dennis L.; Glasson, Christopher R. K.; Norris, Michael R.; Concepcion, Javier J.; Keinan, Shahar; Brennaman, M. Kyle; Templeton, Joseph L.; Meyer, Thomas J. Inorganic Chemistry, 2014 , vol. 53, # 11 p. 5637 - 5646
A systematic synthesis approach for the preparation of a family of phosphonic acid derivatized Ru (II) polypyridyl complexes is reported. Ligand variations are used to vary the electronic structure by incorporating electron-donating or-withdrawing ligands as a way to tune redox properties and excited-state energies. The results of single-mode Franck− Condon analyses of room-temperature steady-state emission spectra are also presented ...
