Kinetics and mechanism of tetrahydrofuran synthesis via 1, 4-butanediol dehydration in high-temperature water

SE Hunter, CE Ehrenberger…

文献索引：Molnar, Arpad; Bartok, Mihaly Helvetica Chimica Acta, 1981 , vol. 64, # 2 p. 389 - 398

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被引用次数: 78

摘要

... 29 In the autoclave reactor used in our work, a much smaller portion of the reactor volume (∼5%) was available for the coexisting vapor phase. ... the heat of reaction to be independent of temperature over the range investigated, one obtains where K' = k F /k' R = (THF)(H 2 O)/(BD ...