A study of the photochemical reactions of 2-cyclohexenones with substituted olefins

EJ Corey, JD Bass, R LeMahieu…

文献索引：Corey,E.J. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 5570 - 5583

全文：HTML全文

被引用次数: 407

摘要

The photochemical reactions of 2-cyclohexenone and other conjugated enones with a variety of unsaturated substances have been investigated to determine the scope, orientation, and stereochemistry of cycloaddition. The occurrence of marked orientational specificity is confirmed as is the frequent formation of trans-fused ring systems. The susceptibility of a number of olefinic substrates to attack by excited 2-cyclohexenone has ...