Kinetics of deprotonation of arylnitromethanes by benzoate ions in acetonitrile solution. Effect of equilibrium and nonequilibrium transition state solvation on intrinsic …

JR Gandler, CF Bernasconi

文献索引：Gandler, Joseph R.; Bernasconi, Claude F. Journal of the American Chemical Society, 1992 , vol. 114, # 2 p. 631 - 637

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被引用次数: 30

摘要

Abstract: Second-order rate constants for benzoate ion promoted deprotonation reactions of (34trophenyl) nitromethane,(4-nitrophenyl) nitromethane, and (3, 5-dinitrophenyl) nitromethane have been determined in acetonitrile solution at 25 OC. These data were obtained at low benzoate buffer concentrations (< 0.01 M), utilizing tetraethylammonium benzoate salts, and benzoate ion concentrations corrected for homoconjugation with data ...