Palladium-catalyzed silylation of alcohols with hexamethyldisilane

E Shirakawa, K Hironaka, H Otsuka…

文献索引：Shirakawa, Eiji; Hironaka, Koji; Otsuka, Hidehito; Hayashi, Tamio Chemical Communications, 2006 , # 37 p. 3927 - 3929

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被引用次数: 23

摘要

The combination of hexamethyldisilane and a catalytic amount of [PdCl (η3-C3H5)] 2–PPh3 was found to be effective for the trimethylsilylation of alcohols, where both of the two trimethylsilyl groups of hexamethyldisilane were transferred to alcohols without coproduction of any stoichiometric amount of byproduct but H2.