Tetrahedron

Soluble and insoluble polymeric 1, 3-dithiane reagents for the synthesis of aldehydes from alkyl halides

V Bertini, F Lucchesini, M Pocci, S Alfei

文献索引：Bertini, Vincenzo; Lucchesini, Francesco; Pocci, Marco; Alfei, Silvana Tetrahedron, 2005 , vol. 61, # 40 p. 9519 - 9526

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被引用次数: 5

摘要

Through the synthesis and study of model systems as proper dithiane derivatives, vinyl monomers and soluble copolymeric reagents containing 2-unsubstituted 1, 3-dithiane rings, we attained the key synthon 1, 3-dithiane-5-methanol. Through its reaction with commercial resins, new polymeric reagents useful for supported organic synthesis and combinatorial chemistry were developed. Exploiting the reactivity of position 2 in 1, 3-dithiane rings, ...