Organic letters

Strategies for the generation of molecularly imprinted polymeric nitroxide catalysts

CD Anderson, KJ Shea, SD Rychnovsky

文献索引：Anderson, Christopher D.; Shea, Kenneth J.; Rychnovsky, Scott D. Organic Letters, 2005 , vol. 7, # 22 p. 4879 - 4882

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被引用次数: 46

摘要

Two strategies for preparing catalytically active molecularly imprinted nitroxide-containing polymers are outlined. Both strategies rely upon the thermal rearrangement chemistry of tertiary amine N-oxides. To this end, several polymers were prepared and the polymeric nitroxides were revealed by oxidation with m-CPBA. All of the resulting polymeric catalysts proved to be competent mediators of the oxidation of alcohols.