Fluorinated derivatives of propane and propylene. VI

AL Henne, TP Waalkes

文献索引：Henne; Waalkes Journal of the American Chemical Society, 1946 , vol. 68, p. 496

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被引用次数: 49

摘要

Electron diffraction measurements have shown that atomic distances are shrunk in polyfluorinated groups. This shrinkage is not restricted to the carbon--fluorine distance, but also affects the carbon to chlorine distance in CC12F2, or the carbon to carbon distance in CFSCHZ. To understand the behavior of polyfluorides, it would be well to learn how far this effect extends down a chain, whether the effect of two polfluorinated groups is cumulative, ...