Reactions of 2, 3, 5-trichloro-4, 4-ethylenedioxy-2-cyclopentenone with some ambident nucleophiles. Sterically loaded functionalized 6-azabicyclo [3.1. 0] hex-5-enes

…, NA Ivanova, FG Usmanova, RR Akhmetvaleev…

文献索引：Shavaleeva; Ivanova; Usmanova; Akhmetvaleev; Miftakhov Russian Journal of Organic Chemistry, 2004 , vol. 40, # 10 p. 1521 - 1525

全文：HTML全文

被引用次数: 3

摘要

Abstract 2, 3, 5-Trichloro-4, 4-ethylenedioxy-2-cyclopentenone reacted with sodium azide in tetrahydrofuran to give the expected 3-azido derivative which was converted into 1, 3- dichloro-4, 4-ethylenedioxy-6-azabicyclo-[3.1. 0] hex-5-en-2-one and 3-amino-2, 5-dichloro- 4, 4-ethylenedioxy-2-cyclopentenone on heating in chloroform. The reaction of 2, 3, 5- trichloro-4, 4-ethylenedioxy-2-cyclopentenone with potassium thiocyanate, depending on ...