Chemistry Letters

REDUCTIVE CONVERSION OF NITRO ALKENES TO KETONES AND/OR OXIMES IN AN AQUEOUS HClO 4–CH 2 Cl 2–DIOXANE–(Pb) SYSTEM

S Torii, H Tanaka, T Katoh

文献索引：Torii, Sigeru; Tanaka, Hideo; Katoh, Tetsuo Chemistry Letters, 1983 , p. 607 - 610

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被引用次数: 18

摘要

Electrochemical and chemical reduction of nitro alkenes in an aqueous HClO 4–CH 2 Cl 2– dioxane–(Pb) system afforded ketones and oximes in good yields, each of which can be obtained selectively by treating with either aqueous formaldehyde or hydroxylamine as a proper workup process, respectively.