Hydrogenation pathway of quinolines over Raney nickel and Ru/C.

…, M Soeda, Y Ikefuji, R Tamura, I Mochida

文献索引：Okazaki, Hiroshi; Onishi, Kiyotaka; Soeda, Mahito; Ikefuji, Yoshio; Tamura, Ryuji; Mochida, Isao Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 11 p. 3167 - 3174

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被引用次数: 13

摘要

Quinoline, 2-methylquinoline, and 8-methylquinoline were hydrogenated over Raney nickel (R-Ni) under 10 atm hydrogen pressure at about 200° C and over ruthenium on carbon (Ru/C) under 100 atm hydrogen pressure at 150° C. All the substrates were commonly hydrogenated into the initial products, 1, 2, 3, 4-tetrahydroquinolines. The initial products were competitively converted over R-Ni to the final products, decahydroquinolines, directly ...