前往化源商城

Thermal Isomerizations of Some Chlorine-Substituted Vinylcyclopropanes

AD Ketley, AJ Berlin, E Gorman…

文献索引:Ketley,A.D. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 305 - 308

全文:HTML全文

被引用次数: 33

摘要

Dichloro-2-vinylcyclopropane yields 4, 4dichlorocyclopentene, 1, l-dichloro-2-methyl-2- vinylcyclopropane yields l-methyl-4, 4dichlorocyclopentene, and 7, 7-dichlorobicyclo [4.1. 0] hept-2-ene yields 4dichloromethylenecyclohexene and benzyl chloride. 1, l-Dichloro-2- cyclopropylprop-l-ene and the isomers of 1-chloro-2-cyclopropylprop-1-ene, however, are stable up to 400'. Above this temperature, extensive decomposition occurs to give mainly ...