Organic & biomolecular chemistry

Highly efficient methods for the one-pot synthesis of β-substituted enones

WJ Kerr, CM Pearson, GJ Thurston

文献索引：Kerr, William J.; Pearson, Colin M.; Thurston, Graeme J. Organic and Biomolecular Chemistry, 2006 , vol. 4, # 1 p. 47 - 50

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被引用次数: 11

摘要

A mild and practically-convenient one-pot procedure for the direct β-substitution of enones has been developed using a conjugate addition–oxidation strategy with a full range of copper-based reagents and N-tert-butylphenylsulfinimidoyl chloride; alkyl-and aryl- substituted enones are delivered in good to excellent yields.