Condensation of a thiol with an isocyanate affords the corresponding thiocarbamate; however, this route was only demonstrated when alkoxy and aroxysulfonyl isocyanates were employed. 6 Moreover, the hydration of a variety of organic thiocyanates has been reported to afford the desired compound in the presence of hydrogen chloride; however, this method is limited to only N,N-unsubstituted thiocarbamates. 19,20 N,N-Disubstituted S-alkyl ...