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The Journal of Organic Chemistry

Reactions of perfluorocycloalkenones with nucleophiles

PJ Card, BE Smart

文献索引:Card, Peter J.; Smart, Bruce E. Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4429 - 4432

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被引用次数: 5

摘要

The reacticins of perfluorocyclopent-2-en-1-one and perfluorocyclobutenone with various nucleophiles have been studied. The enones are attacked by nucleophiles at C-3 via an addition-elimination sequence to afford the 3-substituted perfluorinated enones. Multiple addition products were isolated when the enones were treated with mercaptans. Perfluorocyclopent-2-en-1-one reacted with potassium acetate to give, after hydrolysis, 3- ...