Tetrahedron Letters

An efficient synthesis of hexa-substituted benzenes and the discovery of a novel host conformation for hexakis (β-naphthylthio) benzene

DD MacNicol, PR Mallison, A Murphy, GJ Sym

文献索引：MacNicol, David D.; Mallinson, Paul R.; Murphy, Anthony; Sym, Gordon J. Tetrahedron Letters, 1982 , vol. 23, # 40 p. 4131 - 4134

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被引用次数: 57

摘要

Abstract The title host molecule (III) has been synthesised by reaction of hexachlorobenzene with an excess of the sodium salt of β-mercaptonaphthalene in 1, 3-dimethyl-2- imidazolidinone (DMEU) as solvent; other hexakis (arylthio)-benzenes, hexakis (phenoxy) benzene (IV), and hexakis (phenylseleno) benzene (V) were prepared analogously from hexahalobenzenes, HMPA being used as solvent in the last case. An X-ray analysis of the ...