Journal of the American Chemical Society

Hindered organosilicon compounds. Synthesis and properties of di-tert-butyl-, di-tert-butylmethyl-, and tri-tert-butylsilanes

MP Doyle, CT West

文献索引：Doyle,M.P.; West,C.T. Journal of the American Chemical Society, 1975 , vol. 97, p. 3777 - 3782

全文：HTML全文

被引用次数: 44

摘要

Abstract: Di-tert-butylchlorosilane, but not di-tert-butyldichlorosilane, reacts slowly with alkyllithium compounds to form di-t~ rt-butylalkylsilanes. With methyllithium, substitution is the only observed process. With tert-butyllithium, reduction competes with and is favored over substitution by 2: l. Tri-tert-butylsilane is prepared from tert-butyltrichlorosilane by reac- tion with tert-butyllithium, followed by lithium aluminum hydride reduction of the resulting ...