Journal of the American Chemical Society

Organic sulfur chemistry. 42. Sulfur-sulfur bond cleavage processes. Selective desulfurization of trisulfides

DN Harpp, RA Smith

文献索引：Harpp, David N.; Smith, Roger A. Journal of the American Chemical Society, 1982 , vol. 104, # 22 p. 6045 - 6053

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被引用次数: 70

摘要

Abstract: The selectivity of sulfur removal in the desulfurization of trisulfides by tertiary phosphorus compounds has been investigated in detail. A mechanistic rationalization is proposed to account for central/terminal sulfur extrusion variation as a function of substrate structure and solvent polarity.