Metal??Free SN2′ Decarboxylative Rearrangement of β??Keto Esters

…, J Baudoux, MC Lasne, A Boulangé…

文献索引：Bizet, Vincent; Lefebvre, Valerie; Baudoux, Jerome; Lasne, Marie-Claire; Boulange, Agathe; Leleu, Stephane; Franck, Xavier; Rouden, Jacques European Journal of Organic Chemistry, 2011 , # 22 p. 4170 - 4175

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被引用次数: 3

摘要

Abstract Treatment of 2-methoxycarbonyl-(or 3-cyano-) allyl acetoacetates with a tertiary amine or triphenylphosphane afforded α-methylene γ-substituted δ-keto esters (or nitrile) in satisfactory yields. Various bases and nucleophiles were tested to elucidate the ...