Palladium??Catalyzed Intermolecular C (sp3) H Amidation

Á Iglesias, R Álvarez, ÁR de Lera…

文献索引：Iglesias, Alvaro; Alvarez, Rosana; De-Lera, Angel R.; Muniz, Kilian Angewandte Chemie - International Edition, 2012 , vol. 51, # 9 p. 2225 - 2228

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被引用次数: 97

摘要

The direct amination of C¿ H bonds is a unique synthetic approach towards the important class of alkylated nitrogen compounds.[1] In this context, the palladium-catalyzed intermolecular C (sp3)¿ H activation/amination of alkyl groups is a notably unexplored process.[2–4] On the other hand, we recently came across a reaction based on the formation of alkyl–nitrogen bonds from s-alkyl palladium intermediates in the context of developing ...