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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Transposition des oxirannes-éthanols par l'intermédiaire d'alcoxyétains

JP Bats, J Moulines, P Picard, D Leclercq

文献索引：Bats, J. -P.; Moulines, J.; Picard, P.; Leclercq, D. Tetrahedron, 1982 , vol. 38, # 14 p. 2139 - 2146

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被引用次数: 11

摘要

Oxiraneethoxytributyltins prepared from the corresponding oxiraneethanols, on heating at∼ 200° gave, after demetalation with isophthallic acid, 2-oxetanemethanols and/or 3- oxolanols. As appears from about thirty rearrangements the choice between oxetane and oxolane formation is dependent on:(1) the relative degree of substitution of the oxirane ring; cyclization occuring predominantly at the more substituted carbon; and (2) the ...

2,3-dimethyl-3-(oxiran-2-yl)butan-2-ol结构式

2,3-dimethyl-3-...

~%

(3,3,4,4-tetramethyloxetan-2-yl)methanol结构式

(3,3,4,4-tetram...

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2,4-二甲基-4-戊烯-2-醇结构式

2,4-二甲基-4-戊烯-2-醇

~%

(2,4,4-trimethyloxetan-2-yl)methanol结构式

(2,4,4-trimethy...

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2-methyl-1-(2-methyloxiran-2-yl)propan-2-ol结构式

2-methyl-1-(2-m...

~%

(2,4,4-trimethyloxetan-2-yl)methanol结构式

(2,4,4-trimethy...

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2-(oxiran-2-yl)ethanol结构式

2-(oxiran-2-yl)...

~%

3-羟基四氢呋喃结构式

3-羟基四氢呋喃

2-羟甲基氧杂环丁烷结构式

2-羟甲基氧杂环丁烷

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1-prop-2-enylcyclopentan-1-ol结构式

1-prop-2-enylcy...

~87%

1-(oxiran-2-ylmethyl)cyclopentan-1-ol结构式

1-(oxiran-2-ylm...

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未登录结构式

~%

3-Furanol,tetrahydro-2,2,3,5,5-pentamethyl结构式

3-Furanol,tetra...

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α,α,2,3,3-pentamethyl oxirane-ethanol结构式

α,α,2,3,3-penta...

~%

3-Furanol,tetrahydro-2,2,3,5,5-pentamethyl结构式

3-Furanol,tetra...

2-(2,4,4-trimethyloxetan-2-yl)propan-2-ol结构式

2-(2,4,4-trimet...

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2,3-dimethyl-3-(2-phenyloxiran-2-yl)butan-2-ol结构式

2,3-dimethyl-3-...

~%

(3,3,4,4-tetramethyl-2-phenyloxetan-2-yl)methanol结构式

(3,3,4,4-tetram...

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2,3,3,5-tetramethyl-hex-4-en-2-ol结构式

2,3,3,5-tetrame...

~%

2,2,4,4,5,5-hexamethyloxolan-3-ol结构式

2,2,4,4,5,5-hex...

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3-(3,3-dimethyloxiran-2-yl)-2,3-dimethylbutan-2-ol结构式

3-(3,3-dimethyl...

~%

2,2,4,4,5,5-hexamethyloxolan-3-ol结构式

2,2,4,4,5,5-hex...

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1-(2-methylbut-3-en-2-yl)cyclohexan-1-ol结构式

1-(2-methylbut-...

~88%

1-[2-(oxiran-2-yl)propan-2-yl]cyclohexan-1-ol结构式

1-[2-(oxiran-2-...

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2-甲-4-戊烯-2-醇结构式

2-甲-4-戊烯-2-醇

~%

(4,4-二甲基氧杂环丁烷-2-基)甲醇结构式

(4,4-二甲基氧杂环丁烷-2-基)甲醇

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1-烯丙基环己醇结构式

1-烯丙基环己醇

~%

1-oxaspiro[3.5]nonan-2-ylmethanol结构式

1-oxaspiro[3.5]...

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1-(2-methylbut-3-en-2-yl)cyclohexan-1-ol结构式

1-(2-methylbut-...

~%

(3,3-dimethyl-1-oxaspiro[3.5]nonan-2-yl)methanol结构式

(3,3-dimethyl-1...

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1-[2-(oxiran-2-yl)propan-2-yl]cyclohexan-1-ol结构式

1-[2-(oxiran-2-...

~%

(3,3-dimethyl-1-oxaspiro[3.5]nonan-2-yl)methanol结构式

(3,3-dimethyl-1...

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1-(2-methylprop-2-enyl)cyclohexan-1-ol结构式

1-(2-methylprop...

~%

(2-methyl-1-oxaspiro[3.5]nonan-2-yl)methanol结构式

(2-methyl-1-oxa...

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1-[(2-methyloxiran-2-yl)methyl]cyclohexan-1-ol结构式

1-[(2-methyloxi...

~%

(2-methyl-1-oxaspiro[3.5]nonan-2-yl)methanol结构式

(2-methyl-1-oxa...

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1-(2-methylprop-2-enyl)cyclohexan-1-ol结构式

1-(2-methylprop...

~94%

1-[(2-methyloxiran-2-yl)methyl]cyclohexan-1-ol结构式

1-[(2-methyloxi...

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3-甲基-3-丁烯-1-醇结构式

3-甲基-3-丁烯-1-醇

~%

2-甲基-2-羟基甲基氧杂环丁烷结构式

2-甲基-2-羟基甲基氧杂环丁烷

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