Synthesis and metal-ion binding properties of monoazathiacrown ethers

M Tanaka, M Nakamura, T Ikeda, K Ikeda…

文献索引：Tanaka; Nakamura; Ikeda; Ando; Shibutani; Yajima; Kimura Journal of Organic Chemistry, 2001 , vol. 66, # 21 p. 7008 - 7012

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被引用次数: 56

摘要

Synthetic procedures for monoazathiacrown ethers were explored, and monoazatrithia-12- crown-4, monoazatetrathia-15-crown-5, and monoazapentathia-18-crown-6 were obtained in moderate yields by the reaction of bis (2-chloroethyl) amine with the appropriate dithiols in the presence of lithium hydroxide in THF. To evaluate metal-ion binding properties of the monoazathiacrown ethers by solvent extraction, lipophilic dodecyl and dodecanoyl groups ...