A new synthetic method of preparing iodohydrin and bromohydrin derivatives through in situ generation of hypohalous acids from H5IO6 and NaBrO3 in the presence …

…, M Nishio, A Hasegawa, Y Nishiyama…

文献索引：Masuda, Haruyoshi; Takase, Kiyoshi; Nishio, Masahiro; Hasegawa, Akira; Nishiyama, Yutaka; Ishii, Yasutaka Journal of Organic Chemistry, 1994 , vol. 59, # 19 p. 5550 - 5555

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被引用次数: 101

摘要

Hypohydrous acids such as hypoiodous acid (IOH) and hypobromous acid (BrOH) were found to be easily generated from H5106 and NaBrO3 in the presence of an appropriate reducing agent such as NaHS03. Iodohydrin and bromohydrin derivatives were synthesized in good yields from the reaction of a wide variety of organic compounds bearing carbon- carbon double bonds, with H5IO6 or NaBrOs and NaHS03. The iodohydroxylation of ...