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Model compounds of hydrophilic gels. I. Esters of ethylene glycol and diethylene glycol with pivalic acid

S Ševčík, J Štamberg, M Prochazka

文献索引:Sevcik,S. et al. Collection of Czechoslovak Chemical Communications, 1968 , vol. 33, p. 1327 - 1332

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被引用次数: 11

摘要

The paper describes azeotropic esterification of ethylene glycol and diethylene glycol with pivalic acid, catalysed by the standard (SX 8) and them acroporous (KP-1), strongly acid styrene-divinylbenzene cation exchangers. In agreement with the swelling capacity of polystyrenesulphonic acid in the reaction medium, and in keeping with the lower degree of cross-linking, a higher esterification rate was measured in the use of the standard catalyst. ...