Gas??Phase Reactions of Aliphatic Alcohols with 'Bare'FeO+

…, R Wesendrup, CA Schalley, W Zummack…

文献索引：Schroeder, Detlef; Wesendrup, Ralf; Schalley, Christoph A.; Zummack, Waltraud; Schwarz, Helmut Helvetica Chimica Acta, 1996 , vol. 79, # 1 p. 123 - 132

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被引用次数: 27

摘要

Abstract Ion/molecule reactions of 'bare'FeO+ with linear and branched aliphatic alcohols have been examined by Fourier-transform ion-cyclotron resonance mass spectrometry. Depending on the chain length of the alcohol, three different types of reactions can be distinguished:(i) Oxidation of the alcohols in the α-positions, to yield the corresponding carbonyl-Fe+ complexes, involves an initial O [BOND] H bond activation of the alcohol ...