Synthesis of Biaryls and Oligoarenes Using Aryl [2-(hydroxymethyl) phenyl] dimethylsilanes

J Chen, M Tanaka, AK Sahoo, M Takeda…

文献索引：Chen, Jinshui; Tanaka, Masaaki; Sahoo, Akhila K.; Takeda, Masahide; Yada, Akira; Nakao, Yoshiaki; Hiyama, Tamejiro Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 5 p. 554 - 569

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被引用次数: 29

摘要

Through intramolecular activation, highly stable aryl [2-(hydroxymethyl) phenyl] dimethylsilanes can selectively transfer their aryl groups to effect a cross-coupling reaction with various aryl bromides and chlorides in the presence of a weak non-fluoride base and a palladium/copper catalyst. This reaction tolerates a wide range of functional groups, producing the corresponding functionalized biaryls in high yields with excellent ...