An advantageous synthesis of S-(2-propenyl) N-acylmonothiocarbamates by [3, 3]-sigmatropic rearrangement of O-(2-propenyl) N-acylmonothiocarbamates

P Kutschy, M Dzurilla, D Koščík…

文献索引：Kutschy, Peter; Dzurilla, Milan; Koscik, Dusan; Kristian, Pavol Collection of Czechoslovak Chemical Communications, 1987 ,  vol. 52,  # 7  p. 1764 - 1772

全文：HTML全文

被引用次数: 1

摘要

Abstract Reaction of acetyl, benzoyl, 2-chlorobenzoyl, 3-phenylpropenoyl, 2-naphthoyl, and 3-chloro-2-benzo [b] thienocarbonyl isothiocyanate with 2-propen-1-ol afforded the corresponding O-(2-propenyl) N-acylmonothiocarbamates which underwent [3, 3]- sigmatropic rearrangement on heating in boiling benzene. The reaction represents a simple method for preparation of S-(2-propenyl) N-acylmonothiocarbamates in yields ranging ...