The configuration and tautomeric structure of a variety of amidoximes have been examined. The compounds studied were simple acyclic amidoximes possessing alkyl substituents and cyclic amidoximes including thiomorpholines, piperazines, imidazolidines, and 2- iminothiazolidines. The syntheses of these novel amidoximes are described along with NMR determinations of the stereochemistry of the oxime moiety. Factors determining the ...