Helvetica chimica acta

Refined Insight in Stereochemical and Directional Features of the FeI??Mediated Dehydrogenation of Tetralin

K Seemeyer, H Schwarz

文献索引：Seemeyer, Katrin; Schwarz, Helmut Helvetica Chimica Acta, 1993 , vol. 76, # 6 p. 2384 - 2387

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被引用次数: 3

摘要

Abstract Experimental results demonstrate that, in the course of gas-phase Fe+-mediated dehydrogenation of tetralin, the metal ion sticks to the same plane of the hydrocarbon surface. The study of 5-substituted, labeled tetralin analogues reveal the operation of an interesting substituent effect: Steric hindrance imposed by a CH 3 group at C (5) deflects the metal to the more easily accessible region of C (1)/C (2); in contrast, a CH 3 O substituent ...