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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Vinyl cations. 41. Influence of 4-aryl and 4-alkyl substituents on the. pi.-route solvolyses of homopropargyl esters

CJ Collins, M Hanack, H Stutz, G Auchter…

文献索引：Collins, Clair J.; Hanack, Michael; Stutz, Herbert; Auchter, Gerhard; Schoberth, Winfried Journal of Organic Chemistry, 1983 , vol. 48, # 26 p. 5260 - 5268

全文：HTML全文

被引用次数: 24

摘要

The four 4-substituted-homopropargyl tosylates and triflates 6b-e (R= phenyl, p-tolyl, anisyl, and cyclopropyl) have been synthesized and solvolyzed under various conditions, as have 2- cyclopropyl-1-cyclobutenyl triflate (11-OTf) and nonaflate (11-ONf). In addition, the solvolyses of pent-3-yn-1-yl tosylate (6a-OTs, R= methyl) and triflate (prepared previously) are reported. The ratios of C-3 ring to C-4 ring [R (C3 ring/C, ring)] products are recorded ...

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

详细

乙醇结构式

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

详细

4-methylbenzenesulfonic acid,4-phenylbut-3-yn-1-ol结构式

4-methylbenzene...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

详细

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

3-戊炔-1-醇结构式

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

环丙甲基酮结构式

环丙甲基酮

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

三氟乙醇结构式

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

详细

三氟乙醇结构式

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

3-戊炔-1-醇结构式

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

详细

三氟乙醇结构式

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

4-(4-methoxyphenyl)but-3-yn-1-ol结构式

4-(4-methoxyphe...

~58%

1-but-3-en-1-ynyl-4-methoxybenzene结构式

1-but-3-en-1-yn...

4-甲氧基苯乙炔结构式

4-甲氧基苯乙炔

~%

1-but-3-en-1-ynyl-4-methoxybenzene结构式

1-but-3-en-1-yn...

未登录结构式

~70%

1-but-3-en-1-ynyl-4-methylbenzene结构式

1-but-3-en-1-yn...

4-(4-methylphenyl)but-3-ynyl trifluoromethanesulfonate结构式

4-(4-methylphen...

~%

1-but-3-en-1-ynyl-4-methylbenzene结构式

1-but-3-en-1-yn...

4-乙炔基甲苯结构式

4-乙炔基甲苯

~%

1-but-3-en-1-ynyl-4-methylbenzene结构式

1-but-3-en-1-yn...

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

1,4-dichloro-1-cyclopropylbut-1-ene结构式

1,4-dichloro-1-...

~60%

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

详细

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

1,1'-[Bis(2,2,2-trifluoroethoxy)methylene]biscyclopropane结构式

1,1'-[Bis(2,2,2...

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

详细

三氟乙醇结构式

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

1,1'-[Bis(2,2,2-trifluoroethoxy)methylene]biscyclopropane结构式

1,1'-[Bis(2,2,2...

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

详细

三氟乙醇结构式

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

~%

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

详细

三氟乙醇结构式

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

~%

1-Cyclopropyl-2-(2,2,2-trifluorethoxy)-1-cyclobuten结构式

1-Cyclopropyl-2...

1,1'-[Bis(2,2,2-trifluoroethoxy)methylene]biscyclopropane结构式

1,1'-[Bis(2,2,2...

详细

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

对甲苯磺酰氯(PTSC)结构式

对甲苯磺酰氯(PTSC)

~58%

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

详细

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

环丙基苯基酮结构式

环丙基苯基酮

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

详细

乙醇结构式

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

详细

4-methylbenzenesulfonic acid,4-phenylbut-3-yn-1-ol结构式

4-methylbenzene...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

详细

4-chloro-4-cyclopropylbut-3-en-1-ol结构式

4-chloro-4-cycl...

~90%

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

(2-cyclopropylcyclobuten-1-yl) trifluoromethanesulfonate结构式

(2-cyclopropylc...

~%

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

未登录结构式

双环丙基酮结构式

双环丙基酮

(2-cyclopropylcyclobuten-1-yl) trifluoromethanesulfonate结构式

(2-cyclopropylc...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

未登录结构式

详细

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

详细

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

未登录结构式

详细

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

1-Cyclopropyl-2-(2,2,2-trifluorethoxy)-1-cyclobuten结构式

1-Cyclopropyl-2...

1,1'-[Bis(2,2,2-trifluoroethoxy)methylene]biscyclopropane结构式

1,1'-[Bis(2,2,2...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

详细

三氟乙醇结构式

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

~%

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

详细

醋酸钾结构式

1,4-dichloro-1-cyclopropylbut-1-ene结构式

1,4-dichloro-1-...

~69%

acetic acid,4-chloro-4-cyclopropylbut-3-en-1-ol结构式

acetic acid,4-c...

双环丙基酮结构式

双环丙基酮

~%

acetic acid,4-chloro-4-cyclopropylbut-3-en-1-ol结构式

acetic acid,4-c...

未登录结构式

~49%

1-Pentene-3-yne结构式

1-Pentene-3-yne

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

2-甲基环丁酮结构式

2-甲基环丁酮

详细

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

~%

环丙甲基酮结构式

环丙甲基酮

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

详细

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

3-戊炔-1-醇结构式

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

详细

3-戊炔-1-醇结构式

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

pent-3-ynyl trifluoromethanesulfonate结构式

pent-3-ynyl tri...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

三氟乙醇结构式

3-Pentyn-1-ol,1-(4-methylbenzenesulfonate)结构式

3-Pentyn-1-ol,1...

~%

1-Pentene-3-yne结构式

1-Pentene-3-yne

2-methylcyclobutenyl 2,2,2-trifluoroethyl ether结构式

2-methylcyclobu...

详细

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

~83%

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

环丙基苯基酮结构式

环丙基苯基酮

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

详细

苯乙炔结构式

~%

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

4-methylbenzenesulfonic acid,4-phenylbut-3-yn-1-ol结构式

4-methylbenzene...

~%

环丙基苯基酮结构式

环丙基苯基酮

2-苯基环丁-1-酮结构式

2-苯基环丁-1-酮

Benzene, 3-buten-1-ynyl- (9CI)结构式

Benzene, 3-bute...

详细

未登录结构式

对甲苯磺酰氯(PTSC)结构式

对甲苯磺酰氯(PTSC)

~59%

4-methylbenzenesulfonic acid,4-(4-methylphenyl)but-3-yn-1-ol结构式

4-methylbenzene...

4-(4-methylphenyl)but-3-ynyl trifluoromethanesulfonate结构式

4-(4-methylphen...

~%

4-methylbenzenesulfonic acid,4-(4-methylphenyl)but-3-yn-1-ol结构式

4-methylbenzene...

4-乙炔基甲苯结构式

4-乙炔基甲苯

~%

4-methylbenzenesulfonic acid,4-(4-methylphenyl)but-3-yn-1-ol结构式

4-methylbenzene...

4-甲氧基苯乙炔结构式

4-甲氧基苯乙炔

~%

4-(4-methoxyphenyl)but-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-(4-methoxyphe...

acetic acid,4-chloro-4-cyclopropylbut-3-en-1-ol结构式

acetic acid,4-c...

~87%

4-chloro-4-cyclopropylbut-3-en-1-ol结构式

4-chloro-4-cycl...

1,4-dichloro-1-cyclopropylbut-1-ene结构式

1,4-dichloro-1-...

~%

4-chloro-4-cyclopropylbut-3-en-1-ol结构式

4-chloro-4-cycl...

双环丙基酮结构式

双环丙基酮

~%

4-chloro-4-cyclopropylbut-3-en-1-ol结构式

4-chloro-4-cycl...

环丙基二苯基锍四氟硼酸盐结构式

环丙基二苯基锍四氟硼酸盐

环丙甲醛结构式

~%

2-cyclopropyl-1-oxaspiro[2.2]pentane结构式

2-cyclopropyl-1...

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

苯乙炔结构式

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

溴苯结构式

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

4-methylbenzenesulfonic acid,4-phenylbut-3-yn-1-ol结构式

4-methylbenzene...

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

α-cyclopropylbenzylidenimine hydrochloride结构式

α-cyclopropylbe...

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

三氟乙醇结构式

环丙基苯基酮结构式

环丙基苯基酮

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

三氟乙醇结构式

4-苯基-3-丁炔-1-醇结构式

4-苯基-3-丁炔-1-醇

~%

1-phenyl-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-phenyl-4-(2,2...

4-(4-methylphenyl)but-3-ynyl trifluoromethanesulfonate结构式

4-(4-methylphen...

~%

1-(4-methylphenyl)-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-(4-methylphen...

4-methylbenzenesulfonic acid,4-(4-methylphenyl)but-3-yn-1-ol结构式

4-methylbenzene...

~%

1-(4-methylphenyl)-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-(4-methylphen...

4-乙炔基甲苯结构式

4-乙炔基甲苯

~%

1-(4-methylphenyl)-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-(4-methylphen...

三氟乙醇结构式

未登录结构式

~%

1-(4-methylphenyl)-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-(4-methylphen...

三氟乙醇结构式

环丙基(对甲苯基)甲酮结构式

环丙基(对甲苯基)甲酮

~%

1-(4-methylphenyl)-4-(2,2,2-trifluoroethoxy)butan-1-one结构式

1-(4-methylphen...

1-环丙基甲基-4-甲氧基-苯结构式

1-环丙基甲基-4-甲氧基-苯

~%

2-(4-methoxyphenyl)cyclobutan-1-one结构式

2-(4-methoxyphe...

4-phenylbut-3-ynyl trifluoromethanesulfonate结构式

4-phenylbut-3-y...

~%

4-methylbenzenesulfonic acid,4-phenylbut-3-yn-1-ol结构式

4-methylbenzene...

苯乙炔结构式

~%

4-methylbenzenesulfonic acid,4-phenylbut-3-yn-1-ol结构式

4-methylbenzene...

(3-溴丙基)三苯基溴化磷结构式

(3-溴丙基)三苯基溴化磷

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

1-环丙基甲基-4-甲氧基-苯结构式

1-环丙基甲基-4-甲氧基-苯

(2-cyclopropylcyclobuten-1-yl) trifluoromethanesulfonate结构式

(2-cyclopropylc...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

未登录结构式

详细

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

详细

4-cyclopropylbut-3-ynyl trifluoromethanesulfonate结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

4-cyclopropylbut-3-yn-1-ol结构式

4-cyclopropylbu...

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详细

4-cyclopropylbut-3-yn-1-ol,4-methylbenzenesulfonic acid结构式

4-cyclopropylbu...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

1,1'-[Bis(2,2,2-trifluoroethoxy)methylene]biscyclopropane结构式

1,1'-[Bis(2,2,2...

but-3-en-1-ynylcyclopropane结构式

but-3-en-1-ynyl...

详细

2-cyclopropyl-1-oxaspiro[2.2]pentane结构式

2-cyclopropyl-1...

~%

2-cyclopropylcyclobutan-1-one结构式

2-cyclopropylcy...

Iron salt, a cheap, highly efficient and environment-friendl...

[Yu, Lei; Ren, Lingfeng; Yi, Rong; Wu, Yulan; Chen, Tian; Guo, Rong Journal of Organometallic Chemistry, 2011 , vol. 696, # 10 p. 2228 - 2233]

The first example of asymmetric dihydroxylation of cycloprop...

[Nemoto, Hideo; Miyata, Junji; Hakamata, Hideki; Fukumoto, Keiichiro Tetrahedron Letters, 1995 , vol. 36, # 7 p. 1055 - 1058]

Ring-Enlargement of Dimethylaminopropenoyl Cyclopropanes: An...

[Nakajima, Tadashi; Segi, Masahito; Mituoka, Takeshi; Fukute, Yasuyuki; Honda, Mitsunori; Naitou, Kaneyuki Tetrahedron Letters, 1995 , vol. 36, # 10 p. 1667 - 1670]

First synthesis of (1S, 2S)-and (1R, 2R)-1-amino-2-isopropyl...

[Truong, Molika; Lecornue, Frederic; Fadel, Antoine Tetrahedron Asymmetry, 2003 , vol. 14, # 8 p. 1063 - 1072]

Preparation of Organomercury Compounds

[Shabarov,Yu.S. et al. Doklady Chemistry, 1971 , vol. 198, # 4 p. 477 - 479 Dokl. Akad. Nauk SSSR Ser. Khim., 1971 , vol. 198, # 4 p. 859 - 861]