Journal of organometallic chemistry

The synthesis of chlorosilanes from alkoxysilanes, silanols, and hydrosilanes with bulky substituents

S Masaoka, T Banno, M Ishikawa

文献索引：Masaoka, Shin; Banno, Tadashi; Ishikawa, Mitsuo Journal of Organometallic Chemistry, 2006 , vol. 691, # 1-2 p. 174 - 181

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被引用次数: 10

摘要

We have found that commercially important trialkylchlorosilanes can readily be synthesized by the reaction of alkoxysilanes, silanols, and hydrosilanes with aqueous concentrated hydorochloric acid. Treatment of trialkylalkoxysilanes bearing the bulky alkyl substituents, such as the i-Pr, sec-Bu, tert-Bu, and cyclo-Hex group, with 35% aqueous hydrochloric acid afforded the corresponding trialkylchlorosilanes in excellent yields. Similar treatment of ...