Oxidation of Alcohols to Aldehydes or Ketones with 1??Acetoxy??1, 2??benziodoxole??3 (1H)??one Derivatives

M Iinuma, K Moriyama, H Togo

文献索引：Iinuma, Masataka; Moriyama, Katsuhiko; Togo, Hideo European Journal of Organic Chemistry, 2014 , vol. 2014, # 4 p. 772 - 780

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被引用次数: 4

摘要

Abstract Various benzylic and aliphatic alcohols were smoothly oxidized to the corresponding aromatic aldehydes and ketones as well as aliphatic ketones by treatment with 1-acetoxy-5-nitro-1, 2-benziodoxole-3 (1H)-one (ANBX), 1-acetoxy-5-bromo-1, 2- benziodoxole-3 (1H)-one (ABBX), 1-acetoxy-5-chloro-1, 2-benziodoxole-3 (1H)-one (ACBX), and 1-acetoxy-5-fluoro-1, 2-benziodoxole-3 (1H)-one (AFBX). These new trivalent iodine ...