Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions

…, H Meng, L Jin, F Mo, Y Zhang, J Wang

文献索引：Qiu, Di; Wang, Shuai; Tang, Shengbo; Meng, He; Jin, Liang; Mo, Fanyang; Zhang, Yan; Wang, Jianbo Journal of Organic Chemistry, 2014 , vol. 79, # 5 p. 1979 - 1988

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被引用次数: 14

摘要

A synthetic method based on Sandmeyer-type reactions to access both tin-and boron- substituted arenes from nitroaniline derivatives is described. This transformation can be applied to the synthesis of a series of functionalized trimethylstannyl arylboronates. In addition, the chemoselective reaction of the Stille and Suzuki–Miyaura cross-coupling reactions is explored, and a series of m-and p-terphenyl derivatives have been ...