Bis (pentafluorophenyl) borinic acid as a highly effective Oppenauer oxidation catalyst for allylic and benzylic alcohols

K Ishihara, H Kurihara, H Yamamoto

文献索引：Ishihara, Kazuaki; Kurihara, Hideki; Yamamoto, Hisashi Journal of Organic Chemistry, 1997 , vol. 62, # 17 p. 5664 - 5665

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被引用次数: 52

摘要

Oppenauer (OPP) oxidation is one of the most useful methods for transforming secondary alcohols into ketones. 1, 2 Functional groups such as carbon-carbon double and triple bonds, aldehydes, amino groups, halogens, or sulfur atom-containing groups are not affected by this reaction, which is a great advantage over many oxygentransferring oxidation processes. In general, however, it is difficult to oxidize primary alcohols to the ...