Chemistry letters

Hydroformylation of monosubstituted alkenes catalyzed by W-Rh bimetallic complex

M Yamane, N Yukimura, H Ishiai, K Narasaka

文献索引：Yamane, Motoki; Yukimura, Noriaki; Ishiai, Hiroshi; Narasaka, Koichi Chemistry Letters, 2006 , vol. 35, # 5 p. 540 - 541

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被引用次数: 8

摘要

By using a heterobimetallic catalyst,(CO) 4 (PEtPh 2) W (μ-PPh 2) Rh (CO)(PPh 3), chemoselective hydroformylation of monosubstituted alkenes proceeds efficiently at room temperature under atmospheric pressure of CO/H 2, without affecting functional groups such as disubstituted alkene moieties, aryl and alkenyl iodide moieties, and hydroxy and carboxy groups.