Synlett

A novel, practical synthesis of sulfonyl chlorides from thiol and disulfide derivatives

K Bahrami, MM Khodaei, M Soheilizad

文献索引：Bahrami, Kiumars; Khodaei, Mohammad Mehdi; Soheilizad, Mehdi Synlett, 2009 , # 17 p. 2773 - 2776

全文：HTML全文

被引用次数: 14

摘要

Abstract Hydrogen peroxide, in the presence of zirconium tetrachloride, is a very efficient reagent for the direct oxidative conversion of thiol and disulfide derivatives into the corresponding sulfonyl chlorides with high purity through oxidative chlorination. Excellent yields, very short reaction times, mild reaction conditions, and the avoidance of harsh reagents are the main advantages of this method.