Wacker-Type Oxidation and Dehydrogenation of Terminal Olefins Using Molecular Oxygen as the Sole Oxidant without Adding Ligand

YF Wang, YR Gao, S Mao, YL Zhang, DD Guo…

文献索引：Wang, Yu-Fei; Gao, Ya-Ru; Mao, Shuai; Zhang, Yan-Lei; Guo, Dong-Dong; Yan, Zhao-Lei; Guo, Shi-Huan; Wang, Yong-Qiang Organic Letters, 2014 , vol. 16, # 6 p. 1610 - 1613

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被引用次数: 15

摘要

An efficient and economical palladium-catalyzed oxidation system has been identified. The oxidation system, characterized by not adding ligand and using molecular oxygen as the sole oxidant, can realize the Tsuji–Wacker oxidation of terminal olefins and especially styrenes to methyl ketones; in addition, this system can achieve tandem Wacker oxidation– dehydrogenation of terminal olefins to α, β-unsaturated ketones.

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1667-01-2

2',4',6'-三甲基苯乙酮

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~93%

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~97%

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~98%

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~88%

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