Synthetic Communications

Simplified Procedure for TEMPO-Catalyzed Oxidation: Selective Oxidation of Alcohols, α-Hydroxy Esters, and Amides Using TEMPO and Calcium Hypochlorite

SR Reddy, S Stella, A Chadha

文献索引：Reddy, Sabbasani Rajasekhara; Stella, Selvaraj; Chadha, Anju Synthetic Communications, 2012 , vol. 42, # 23 p. 3493 - 3503

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被引用次数: 12

摘要

Calcium hypochlorite has been used for ring chlorination of activated benzenoid compounds [6a] and oxidation of aldehydes [6b] alcohols [6c,d] sulfides, [6e] and uronates. [6f] Notably, α-hydroxy carbonyl compounds have been reported to get converted to aldehydes or carboxylic acids in the presence of calcium hypochlorite/acetic acid/acetonitrile [6g] instead of giving α-keto carbonyl compounds. This catalytic system is also known to oxidize α-diketones and ...